Water quality. Application of inductively coupled plasma mass spectrometry (ICP-MS) - Determination of selected elements including uranium isotopes
Water quality. Application of inductively coupled plasma mass spectrometry (ICP-MS) - Determination of selected elements including uranium isotopes
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Water quality. Application of inductively coupled plasma mass spectrometry (ICP-MS) - Determination of selected elements including uranium isotopes

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1   Scope

This document specifies a method for the determination of the elements aluminium, antimony, arsenic, barium, beryllium, bismuth, boron, cadmium, caesium, calcium, cerium, chromium, cobalt, copper, dysprosium, erbium, gadolinium, gallium, germanium, gold, hafnium, holmium, indium, iridium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, mercury, molybdenum, neodymium, nickel, palladium, phosphorus, platinum, potassium, praseodymium, rubidium, rhenium, rhodium, ruthenium, samarium, scandium, selenium, silver, sodium, strontium, terbium, tellurium, thorium, thallium, thulium, tin, titanium, tungsten, uranium and its isotopes, vanadium, yttrium, ytterbium, zinc and zirconium in water (e.g. drinking water, surface water, ground water, waste water and eluates).
Taking into account the specific and additionally occurring interferences, these elements can be determined in water and digests of water and sludge (e.g. digests of water as described in ISO 15587‑1 or ISO 15587‑2).
The working range depends on the matrix and the interferences encountered. In drinking water and relatively unpolluted waters, the limit of quantification (LOQ) lies between 0,002 µg/l and 1,0 µg/l for most elements (see Table 1). The working range typically covers concentrations between several ng/l and mg/l depending on the element and specified requirements.
The quantification limits of most elements are affected by blank contamination and depend predominantly on the laboratory air-handling facilities available on the purity of reagents and the cleanliness of glassware.
The lower limit of quantification is higher in cases where the determination suffers from interferences (see Clause 5) or memory effects (see ISO 17294‑1).
Elements other than those mentioned in the scope can also be determined according to this document provided that the user of the document is able to validate the method appropriately (e.g. interferences, sensitivity, repeatability, recovery).
Table 1Lower limits of quantification for unpolluted water
Element Isotope often used L OQ a Element Isotope often used L OQ a Element Isotope often used L OQ a
µg/l µg/l µg/l
Ag 107Ag 0,5 Hf 178Hf 0,1 Ru 102Ru 0,1
109Ag 0,5 Hg 202Hg 0,05 Sb 121Sb 0,2
201Hg 0,1
Al 27Al 1 Ho 165Ho 0,1 123Sb 0,2
As 75Asc 0,1 In 115In 0,1 Sc 45Sc 5
Au 197Au 0,5 Ir 193Ir 0,1 Se 77Sec 1
B 10B 1 K 39KC 5 78Sec 0,1
11B 1 La 139La 0,1 82Se 1
Ba 137Ba 3 Li 6Li 10 Sm 147Sm 0,1
138Ba 0,5 7Li 1 Sn 118Sn 1
Be 9Be 0,1 Lu 175Lu 0,1 120Sn 1
Bi 209Bi 0,5 Mg 24Mg 1 Sr 86Sr 0,5
Ca 43Ca 100 25Mg 10 88Sr 0,3
44Ca 50 Mn 55Mn 0,1 Tb 159Tb 0,1
40Ca 10 Mo 95Mo 0,5 Te 126Te 2
Cd 111Cd 0,1 98Mo 0,3 Th 232Th 0,1
114Cd 0,5 Na 23Na 10 Tl 203Tl 0,2
Ce 140Ce 0,1 Nd 146Nd 0,1 205Tl 0,1
Ti 47Ti 10
48Ti 1
49Ti 10
Co 59Co 0,2 Ni 58Nic 0,1 Tm 169Tm 0,1
Cr 52Crc 0,1 60Nic 0,1 U 238U 0,1
53Cr 5 P 31P 5 235U 1,10−4
Cs 133Cs 0,1 Pb 206Pbb 0,2 234U 1,10−5
Cu 63Cu 0,1 207Pbb 0,2 V 51Vc 0,1
65Cu 0,1 208Pbb 0,1 W 182W 0,3
Dy 163Dy 0,1 Pd 108Pd 0,5 184W 0,3
Er 166Er 0,1 Pr 141Pr 0,1 Y 89Y 0,1
Fe 56Fec 5 Pt 195Pt 0,5 Yb 172Yb 0,2
Ga 69Ga 0,3 Rb 85Rb 0,1 174Yb 0,2
71Ga 0,3 Re 185Re 0,1 Zn 64Zn 1
Gd 157Gd 0,1 187Re 0,1 66Zn 1
158Gd 0,1 Rh 103Rh 0,1 68Zn 1
Ge 74Ge 0,3 Ru 101Ru 0,2 Zr 90Zr 0,2
a Depending on the instrumentation, significantly lower limits can be achieved.
b Lead (Pb) is reported as the sum of the signal intensities of 206Pb, 207Pb and 208Pb.
c These limits are achieved by the use of a collision/reaction cell.